520748
Palladium(II) oxide
99.97% trace metals basis
Synonym(s):
Palladium monoxide, Palladium oxide
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About This Item
Empirical Formula (Hill Notation):
OPd
CAS Number:
Molecular Weight:
122.42
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352303
EC Number:
215-218-3
MDL number:
InChI key
HBEQXAKJSGXAIQ-UHFFFAOYSA-N
InChI
1S/O.Pd
SMILES string
O=[Pd]
assay
99.97% trace metals basis
form
powder and chunks
composition
Pd, 85-87%
reaction suitability
reagent type: catalyst
core: palladium
mp
870 °C (lit.)
density
8.7 g/mL at 25 °C (lit.)
Quality Level
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General description
Palladium(II) oxide (PdO) is a p-type semiconductor with a band gap of 2.2-2.7 eV. It is widely used as an efficient catalyst for oxidation reactions of hydrocarbons and for fabrication of gas sensors.
Application
Ceria supported Palladium(II) oxide can be used as a catalyst for ozonation of oxalate, to enhance the degradation of recalcitrant organics in polluted water. PdO provides active sites for the decomposition of ozone to surface atomic oxygen. Itcan be used as a cocatalyst for partial oxidation of alcohols on the WO3catalyst.
Storage Class
5.1B - Oxidizing hazardous materials
signalword
Danger
hcodes
Hazard Classifications
Ox. Sol. 2
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Tao Zhang et al.
Environmental science & technology, 45(21), 9339-9346 (2011-10-06)
The cerium supported palladium oxide (PdO/CeO(2)) at a low palladium loading was found very effective in catalytic ozonation of oxalate, a probe compound that is difficult to be efficiently degraded in water with hydroxyl radical oxidation and one of the
Bas L M Hendriksen et al.
Nature chemistry, 2(9), 730-734 (2010-08-24)
Atomic steps at the surface of a catalyst play an important role in heterogeneous catalysis, for example as special sites with increased catalytic activity. Exposure to reactants can cause entirely new structures to form at the catalyst surface, and these
Sylvain Duval et al.
Dalton transactions (Cambridge, England : 2003), 41(11), 3174-3184 (2012-01-31)
Heterometallic cuboidal clusters [Mo(3)S(4)M(H(2)O)(9)Cl](3+) M = Pd or Ni react with the trivacant [AsW(9)O(33)](9-) anion to give tetramodular complexes [(H(2)AsW(9)O(33))(4){Mo(3)S(4)M(H(2)O)(5)}(2)](20-) (M = Pd for anion 2 and M = Ni for anion 3) in good yield. Both anions crystallized as
Structural and redox properties of VOx and Pd/VOx thin film model catalysts studied by TEM and SAED.
Simon Penner et al.
Physical chemistry chemical physics : PCCP, 9(19), 2428-2433 (2007-05-12)
The oxidation of pure V(2)O(3) and Pd/V(2)O(3) films was studied by Transmission Electron Microscopy (TEM) and Selected Area Electron Diffraction (SAED) in the temperature range 673-773 K. Thin films of V(2)O(3) were prepared by reactive deposition of V metal in
A Pd-PdO film potentiometric pH sensor.
V A Karagounis et al.
IEEE transactions on bio-medical engineering, 33(2), 113-116 (1986-02-01)
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