521590
1-Chloro-5-iodopentane
97%
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About This Item
Linear Formula:
I(CH2)5Cl
CAS Number:
Molecular Weight:
232.49
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Assay
97%
SMILES string
ClCCCCCI
InChI
1S/C5H10ClI/c6-4-2-1-3-5-7/h1-5H2
InChI key
GUUHKOCYWBEGGX-UHFFFAOYSA-N
General description
1-Chloro-5-iodopentane is a halogenated hydrocarbon. 1,10-dichlorododecane is formed as a major product from the reduction of 1-chloro-5-iodohexane with electrogenerated nickel(I) salen [salen = N,N′-bis(salicylidene)ethylenediamine]. Its IR spectra in liquid and solid states have been studied. It affords dimer radical cation on reaction with OH radicals. Synthesis of 1-chloro-5-iodopentane starting from 1,5-dichloropentane has been reported.
Application
1-Chloro-5-iodopentane may be used in the synthesis of 2-(tert-butyldimet hylsiloxy)-11-chloro-5-undecyne and cis-7-dodecen-1-ol acetate.
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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S Lindstedt et al.
Clinical chemistry, 22(8), 1330-1338 (1976-08-01)
Gas chromatography/mass spectrometry was used to identify a series of acids in urine and serum from a child who died 26 h after birth in severe metabolic acidosis with high lactate excretion. cis-5-Decene-1, 10-dioic acid and cis-5-dodencene-1, 12-dioic acid were
Transformation of OH-adduct of 1-chloro-4-iodobutane into intra-molecular radical cation in neutral aqueous solution.
Mohan H, et al.
Chemical Physics Letters, 300(3), 493-498 (1999)
Synthesis of two macrolide aggregation pheromones from the flat grain beetle, Cryptolestes pusillus (Schonherr).
Millar JC, et al.
The Journal of Organic Chemistry, 48(23), 4404-4407 (1983)
Insect sex attractants. VI. 7-dodecen-1-ol acetates and congeners.
N Green et al.
Journal of medicinal chemistry, 10(4), 533-535 (1967-07-01)
Conformational analysis of 1-chloro-4-iodobutane and 1-chloro-5-iodopentane.
Crowder G and Ali S.
Journal of Molecular Structure, 34(1), 47-53 (1976)
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