525111
3-Methyl-2-thienylzinc bromide solution
0.5 M in THF
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About This Item
Empirical Formula (Hill Notation):
C5H5BrSZn
CAS Number:
Molecular Weight:
242.45
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C5H5S.BrH.Zn/c1-5-2-3-6-4-5;;/h2-3H,1H3;1H;/q;;+1/p-1
SMILES string
Cc1ccsc1[Zn]Br
InChI key
KNFCPQJOQLKVRD-UHFFFAOYSA-M
concentration
0.5 M in THF
bp
65 °C
density
0.978 g/mL at 25 °C
storage temp.
2-8°C
Application
3-Methyl-2-thienylzinc bromide can be used as a starting material for the synthesis of thiophene-containing natural products pyridoacridines.
Legal Information
Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
signalword
Danger
target_organs
Central nervous system, Respiratory system
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3 - Water-react. 2
Regulatory Information
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Synthesis of pyridoacridines through anionic cascade ring closure
Petersen IN and Kristensen JL
Synthesis, 46(11), 1469-1474 (2014)
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