525685
双联(2-甲基-2,4-戊二醇)硼酸酯
96%
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关于此项目
经验公式（希尔记法）:
C12H24B2O4
化学文摘社编号:
分子量:
253.94
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
Quality Segment
assay
96%
mp
98-102 °C (lit.)
SMILES string
CC1CC(C)(C)OB(O1)B2OC(C)CC(C)(C)O2
InChI
1S/C12H24B2O4/c1-9-7-11(3,4)17-13(15-9)14-16-10(2)8-12(5,6)18-14/h9-10H,7-8H2,1-6H3
InChI key
UEBSWKNVDRJVHN-UHFFFAOYSA-N
Application
Bis(hexylene glycolato)diboron can be used as a reagent:
- To prepare aryl boronate esters via metal-catalyzed direct C-H borylation of aryl compounds.
- In the chemoselective synthesis of C−C coupling products via nickel catalyzed coupling of primary and secondary alkyl halides.
- In the nickel-catalyzed regioselective arylboration of terminal nonactivated alkenes to yield alkyl boranes.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)