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528544

3-Methoxy-2-naphthoic acid

Name: 3-Methoxy-2-naphthoic acid
Brand: ALDRICH

98%

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About This Item

Linear Formula:

CH₃OC₁₀H₆CO₂H

CAS Number:

883-62-5

Molecular Weight:

202.21

NACRES:

NA.22

PubChem Substance ID:

24877595

UNSPSC Code:

12352100

EC Number:

212-932-7

MDL number:

MFCD00094168

Assay:

98%

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Properties

assay

98%

mp

133-136 °C (lit.)

SMILES string

COc1cc2ccccc2cc1C(O)=O

InChI

1S/C12H10O3/c1-15-11-7-9-5-3-2-4-8(9)6-10(11)12(13)14/h2-7H,1H3,(H,13,14)

InChI key

RTBQQRFTCVDODF-UHFFFAOYSA-N

Description

General description

3-Methoxy-2-naphthoic acid is a naphthoic acid derivative. 3-Methoxy-2-naphthoic acid can be prepared from 3-hydroxy-2-naphthoic acid, via methylation. It undergoes reduction under the following reaction conditions:

in the presence of Li and NH₄Cl to afford 1,2,3,4-tetrahydro-2-naphthoic acid
by using Li, NH₄Cl and anhydrous FeCl₃ to afford 3-methoxy-1, 2-dihydro-2-naphthoic acid
in anhydrous ether, liquid ammonia, lithium wire and anhydrous ethanol to afford 1,2,3,4-tetrahydro-2-naphthoic acid

Application

3-Methoxy-2-naphthoic acid may be used in the synthesis of N-[p-N,N-dimethylanilino)-3-methoxy-2-naphtho]hydroxamic acid (DAMNHA).

ppe

Eyeshields, Gloves, type N95 (US)

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Extraction and spectrophotometric determination of vanadium (V) with N-[p-(N, N-dimethylanilino)-3-methoxy-2-naphtho] hydroxamic acid.

Abbasi S.

Analytical Chemistry, 48(4), 714-717 (1976)

Studies in metal-ammonia reduction-5: Reduction and reductive methylation of some naphthoic acids.

Murthy AR, et al.

Tetrahedron, 38(18), 2831-2836 (1982)

Antihyperglycemic activity of novel naphthalenyl 3H-1,2,3,5-oxathiadiazole 2-oxides.

J W Ellingboe et al.

Journal of medicinal chemistry, 36(17), 2485-2493 (1993-08-20)

A series of naphthalenyl 3H-1,2,3,5-oxathiadiazole 2-oxides was prepared and tested for antihyperglycemic activity in the db/db mouse, a model for type 2 (non-insulin dependent) diabetes mellitus. Substitution at the 1-, 5-, or 8-positions of the naphthalene ring with a halogen

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Global Trade Item Number

SKU	GTIN
528544-1G	04061825585840