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Merck
CN

531081

N-Hydroxynaphthalimide triflate

electronic grade, ≥99%

Synonym(s):

N-Hydroxynaphthalimide trifluoromethanesulfonate, HNT, NHN-TF

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About This Item

Empirical Formula (Hill Notation):
C13H6F3NO5S
CAS Number:
85342-62-7
Molecular Weight:
345.25
NACRES:
NA.23
PubChem Substance ID:
24877801
UNSPSC Code:
12352300
MDL number:
MFCD02683478

Key Documents

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Product Name

N-Hydroxynaphthalimide triflate, electronic grade, ≥99%

assay

≥99%

InChI

1S/C13H6F3NO5S/c14-13(15,16)23(20,21)22-17-11(18)8-5-1-3-7-4-2-6-9(10(7)8)12(17)19/h1-6H

SMILES string

FC(F)(F)S(=O)(=O)ON1C(=O)c2cccc3cccc(C1=O)c23

InChI key

LWHOMMCIJIJIGV-UHFFFAOYSA-N

grade

electronic grade

mp

212.1-214.2 °C

solubility

PGMEA: 1%
ethyl lactate: <1%
γ-butyrolactone: ~2%

Related Categories

Application

HNT can be used to form patterned nanoparticles that find potential applications in volumetric manufacturing of semiconductor devices. It can also be used in the photo-responsive pore reopening of zeolites that facilitates the regulation of the gas permeation process. UV-irradiated trimethylsilyl ultrathin cellulose based films can be formed in presence of HNT as a PAG.

General description

N-Hydroxynaphthalimide triflate (HNT) is a photoacid generator(PAG) that forms an acid upon exposure to UV light which can be used to generate patterned structures. It can also be used to tune the solubility of a polymer by forming acid linkages.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
MKCL5273
04301LC

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Rajeev N Bahuguna et al.
Physiologia plantarum, 159(1), 59-73 (2016-08-16)
High night temperature (HNT) is a major constraint to sustaining global rice production under future climate. Physiological and biochemical mechanisms were elucidated for HNT-induced grain yield and quality loss in rice. Contrasting rice cultivars (N22, tolerant; Gharib, susceptible; IR64, high
Surface modification of zeolites using benzene-1, 4-diboronic acid to form gated micropores with mild and photo responsive pore reopening
Fujiwara M, et al.
Chemical Engineering Journal, 146(3), 520-526 (2009)
Jayabrata Maity et al.
Carbohydrate polymers, 182, 159-171 (2017-12-28)
Composite type adsorbent was prepared by integrating chitosan (Cs) with crosslinked polymethacrylic acid (PMA) and nano sized halloysite nanotube (HNT). The structure of the resulting Cs-PMA/HNT adsorbents was characterized by FTIR, NMR, XRD, TGA, SEM/EDX and rheological properties. These functional
Non-ionic photo-acid generators for applications in two-photon lithography
Steidl L, et al.
Journal of Materials Chemistry, 19(4), 505-513 (2009)
Selin S Suner et al.
International journal of biological macromolecules, 130, 627-635 (2019-03-07)
We present here preparation of mechanically strong and biocompatible cryogel composites based on hyaluronic acid (HA) and halloysite nanotubes (HNTs) of various compositions, and their applications as scaffold for different cell growing media. Uniaxial compression tests reveal that the incorporation
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