531081
N-Hydroxynaphthalimide triflate
electronic grade, ≥99%
Synonym(s):
N-Hydroxynaphthalimide trifluoromethanesulfonate, HNT, NHN-TF
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About This Item
Empirical Formula (Hill Notation):
C13H6F3NO5S
CAS Number:
Molecular Weight:
345.25
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.23
grade
electronic grade
Assay
≥99%
mp
212.1-214.2 °C
solubility
PGMEA: 1%
ethyl lactate: <1%
γ-butyrolactone: ~2%
SMILES string
FC(F)(F)S(=O)(=O)ON1C(=O)c2cccc3cccc(C1=O)c23
InChI
1S/C13H6F3NO5S/c14-13(15,16)23(20,21)22-17-11(18)8-5-1-3-7-4-2-6-9(10(7)8)12(17)19/h1-6H
InChI key
LWHOMMCIJIJIGV-UHFFFAOYSA-N
Related Categories
General description
N-Hydroxynaphthalimide triflate (HNT) is a photoacid generator(PAG) that forms an acid upon exposure to UV light which can be used to generate patterned structures. It can also be used to tune the solubility of a polymer by forming acid linkages.
Application
HNT can be used to form patterned nanoparticles that find potential applications in volumetric manufacturing of semiconductor devices. It can also be used in the photo-responsive pore reopening of zeolites that facilitates the regulation of the gas permeation process. UV-irradiated trimethylsilyl ultrathin cellulose based films can be formed in presence of HNT as a PAG.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Rajeev N Bahuguna et al.
Physiologia plantarum, 159(1), 59-73 (2016-08-16)
High night temperature (HNT) is a major constraint to sustaining global rice production under future climate. Physiological and biochemical mechanisms were elucidated for HNT-induced grain yield and quality loss in rice. Contrasting rice cultivars (N22, tolerant; Gharib, susceptible; IR64, high
Surface modification of zeolites using benzene-1, 4-diboronic acid to form gated micropores with mild and photo responsive pore reopening
Fujiwara M, et al. 
Chemical Engineering Journal, 146(3), 520-526 (2009)
Non-ionic photo-acid generators for applications in two-photon lithography
Steidl L, et al. 
Journal of Materials Chemistry, 19(4), 505-513 (2009)
Jan Kendall de Kruif et al.
European journal of pharmaceutics and biopharmaceutics : official journal of Arbeitsgemeinschaft fur Pharmazeutische Verfahrenstechnik e.V, 101, 90-102 (2016-02-07)
Newly discovered active macromolecules are highly promising for therapy, but poor bioavailability hinders their oral use. Microencapsulation approaches, such as protein prilling into microspheres, may enable protection from gastrointestinal (GI) enzymatic degradation. This would increase bioavailability mainly for local delivery
Photoregeneration of trimethylsilyl cellulose as a tool for microstructuring ultrathin cellulose supports
Wolfberger A, et al. 
Molecules (Basel), 19(10), 16266-16273 (2014)
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