532894
Methyl 2,5-dibromobenzoate
99%
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About This Item
Linear Formula:
Br2C6H3CO2CH3
CAS Number:
Molecular Weight:
293.94
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
99%
InChI
1S/C8H6Br2O2/c1-12-8(11)6-4-5(9)2-3-7(6)10/h2-4H,1H3
SMILES string
COC(=O)c1cc(Br)ccc1Br
InChI key
RBCUIRIGTNHLPS-UHFFFAOYSA-N
assay
99%
mp
48-51 °C (lit.)
functional group
bromo, ester
General description
Methyl 2,5-dibromobenzoate, an aromatic ester, can be prepared from 2,5-dibromobenzoic acid via esterification with methanol. It undergoes Ni(0)-catalyzed polymerization to form soluble polyphenylenes.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Synthesis of functional poly (p-phenylene)s from substituted hydroquinones via nickel-catalyzed coupling of their bistriflates.
Percec V, et al.
Macromolecules, 25(6), 1816-1823 (1992)
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