537837
2-Methyl-4-nitroanisole
97%
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About This Item
Linear Formula:
CH3C6H3(NO2)OCH3
CAS Number:
Molecular Weight:
167.16
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
256-748-5
MDL number:
Assay:
97%
Product Name
2-Methyl-4-nitroanisole, 97%
InChI key
QOZMIJZYJZQOBV-UHFFFAOYSA-N
InChI
1S/C8H9NO3/c1-6-5-7(9(10)11)3-4-8(6)12-2/h3-5H,1-2H3
SMILES string
COc1ccc(cc1C)[N+]([O-])=O
assay
97%
mp
61-64 °C (lit.)
functional group
nitro
Application
2-Methyl-4-nitroanisole may be used in the synthesis of 2-methyl-4-nitrophenol and 3-methyl-4-methoxyaniline.
General description
2-Methyl-4-nitroanisole is obtained as one of the products from the charge-transfer trinitromethylation of 2-methylanisole in the presence of dichloromethane.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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5-Methyl-6-methoxy-8-(2'-diethylaminoethylamino)-quinoline1.
Carmack M, et al.
Journal of the American Chemical Society, 68(8), 1551-1552 (1946)
Studies on photochemical reaction of air pollutants. X. Identification of nitrophenols in suspended particulates.
Nojima K, et al.
Chemical & Pharmaceutical Bulletin, 31(3), 1047-1051 (1983)
Annihilation of aromatic cation radicals by ion-pair and radical pair collapse. Unusual solvent and salt effects in the competition for aromatic substitution.
Sankararaman S, et al.
Journal of the American Chemical Society, 109(25), 7824- 7838 (1987)
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