539147
Ethyl chlorofluoroacetate
98%
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About This Item
Linear Formula:
Cl(F)CHCO2C2H5
CAS Number:
Molecular Weight:
140.54
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
206-930-5
MDL number:
Product Name
Ethyl chlorofluoroacetate, 98%
InChI key
WUHVJSONZHSDFC-UHFFFAOYSA-N
InChI
1S/C4H6ClFO2/c1-2-8-4(7)3(5)6/h3H,2H2,1H3
SMILES string
CCOC(=O)C(F)Cl
assay
98%
refractive index
n20/D 1.396 (lit.)
bp
133 °C (lit.)
density
1.212 g/mL at 25 °C (lit.)
functional group
chloro
ester
fluoro
Quality Level
Application
Ethyl chlorofluoroacetate may be used in the synthesis of:
- chlorofluoroacetamide
- ethyl α-fluoro silyl enol ether
- chlorofluoroacetyl chloride
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 3 - Skin Corr. 1B
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
125.0 °F - closed cup
flash_point_c
51.67 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
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Xiao-Ting Huang et al.
The Journal of organic chemistry, 67(10), 3231-3234 (2002-05-11)
Ethyl alpha-fluoro silyl enol ether is stereoselectively synthesized in high yield from inexpensive chlorofluoroacetate and Mg (or Zn) in DMF (or HMPA). Lewis acid promoted aldol reaction of this enol ether with aldehydes and ketones gives alpha-fluoro-beta-hydroxy esters in good
The preparation of some derivatives of chlorofluoroacetic acid.
Young JA and Tarrant P.
Journal of the American Chemical Society, 71(1), 3278-3285 (1949)
One-step method for converting esters to acyl chlorides.
Middleton WJ.
The Journal of Organic Chemistry, 44(13), 2291-2292 (1979)
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