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Merck
CN

540129

(2S)-(+)-Glycidyl tosylate

98%

Synonym(s):

(S)-(+)-Glycidyl p-toluenesulfonate, (S)-(+)-Oxirane-2-methanol p-toluenesulfonate

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About This Item

Empirical Formula (Hill Notation):
C10H12O4S
CAS Number:
70987-78-9
Molecular Weight:
228.26
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
24878443
EC Number:
417-210-7
Beilstein/REAXYS Number:
3592143
MDL number:
MFCD00064489
Assay:
98%

Key Documents

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InChI key

NOQXXYIGRPAZJC-VIFPVBQESA-N

InChI

1S/C10H12O4S/c1-8-2-4-10(5-3-8)15(11,12)14-7-9-6-13-9/h2-5,9H,6-7H2,1H3/t9-/m0/s1

SMILES string

Cc1ccc(cc1)S(=O)(=O)OC[C@@H]2CO2

assay

98%

Quality Level

100

functional group

ether, tosylate

storage temp.

2-8°C

Related Categories

Application

Used in the first enantioselective synthesis of (R)- and (S)-4-acetyl-3-(hydroxymethyl)-3,4-dihydro-2H-pyrido[3,2-b]oxazines.

Legal Information

Manufactured under license by Sterling Pharma Solutions Limited, using Jacobsen HKR technology.

signalword

Danger

Hazard Classifications

Aquatic Chronic 2 - Carc. 1B - Eye Dam. 1 - Muta. 2 - Skin Sens. 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKAA2935V
MKBD1362
MKAA2935
09221BJ
06124DJ

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Henry, N. et al.
Tetrahedron Letters, 45, 1465-1465 (2004)

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