540390
(3,4-Dihydro-1-naphthyloxy)trimethylsilane
97%
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About This Item
Empirical Formula (Hill Notation):
C13H18OSi
CAS Number:
Molecular Weight:
218.37
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
InChI
1S/C13H18OSi/c1-15(2,3)14-13-10-6-8-11-7-4-5-9-12(11)13/h4-5,7,9-10H,6,8H2,1-3H3
SMILES string
C[Si](C)(C)OC1=CCCc2ccccc12
InChI key
CAUIWDWUUCGKBV-UHFFFAOYSA-N
assay
97%
refractive index
n20/D 1.5287 (lit.)
bp
63-65 °C/0.01 mmHg (lit.)
density
0.983 g/mL at 25 °C (lit.)
Quality Level
General description
(3,4-Dihydro-1-naphthyloxy)trimethylsilane (3,4-dihydronaphthalen-1-yloxy(trimethyl)silane) is a protected phenol. Its IR spectral analysis suggests νmax (DCM) = 1638cm-1.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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William J Kerr et al.
Chemical communications (Cambridge, England), (47)(47), 5049-5051 (2007-12-01)
Bismesitylmagnesium has been established as an accessible, practical, convenient, and non-nucleophilic carbon-centred base reagent for efficient access to silyl enol ethers from a series of ketone substrates at readily utilisable temperatures.
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