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540390

(3,4-Dihydro-1-naphthyloxy)trimethylsilane

Name: (3,4-Dihydro-1-naphthyloxy)trimethylsilane
Brand: ALDRICH

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About This Item

Empirical Formula (Hill Notation):

C₁₃H₁₈OSi

CAS Number:

38858-72-9

Molecular Weight:

218.37

NACRES:

NA.22

PubChem Substance ID:

24878464

UNSPSC Code:

12352100

MDL number:

MFCD03093969

Assay:

97%

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Properties

Quality Level

100

assay

97%

refractive index

n20/D 1.5287 (lit.)

bp

63-65 °C/0.01 mmHg (lit.)

density

0.983 g/mL at 25 °C (lit.)

SMILES string

C[Si](C)(C)OC1=CCCc2ccccc12

InChI

1S/C13H18OSi/c1-15(2,3)14-13-10-6-8-11-7-4-5-9-12(11)13/h4-5,7,9-10H,6,8H2,1-3H3

InChI key

CAUIWDWUUCGKBV-UHFFFAOYSA-N

Description

General description

(3,4-Dihydro-1-naphthyloxy)trimethylsilane (3,4-dihydronaphthalen-1-yloxy(trimethyl)silane) is a protected phenol. Its IR spectral analysis suggests ν_max (DCM) = 1638cm^-1.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Bismesitylmagnesium: a thermally stable and non-nucleophilic carbon-centred base reagent for the efficient preparation of silyl enol ethers.

William J Kerr et al.

Chemical communications (Cambridge, England), (47)(47), 5049-5051 (2007-12-01)

Bismesitylmagnesium has been established as an accessible, practical, convenient, and non-nucleophilic carbon-centred base reagent for efficient access to silyl enol ethers from a series of ketone substrates at readily utilisable temperatures.