540595
(S)-(−)-3,3′-Dibromo-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-bi-2,2′-naphthalenediol
97%
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About This Item
Empirical Formula (Hill Notation):
C20H20Br2O2
CAS Number:
Molecular Weight:
452.18
PubChem Substance ID:
UNSPSC Code:
12352101
MDL number:
InChI
1S/C20H20Br2O2/c21-15-9-11-5-1-3-7-13(11)17(19(15)23)18-14-8-4-2-6-12(14)10-16(22)20(18)24/h9-10,23-24H,1-8H2
InChI key
WDRTXCNGVVLRSZ-UHFFFAOYSA-N
assay
97%
optical activity
[α]20/D −53°, c = 1 in THF
mp
145.5-148.5 °C (lit.)
functional group
bromo
General description
(S)-3,3′-Dibromo-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-bi-2,2′-naphthalenediol can be used in the synthesis of chiral bidentate hybrid ligands for asymmetric hydrogenation and hydroformylation reactions.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Coordination studies on supramolecular chiral ligands and application in asymmetric hydroformylation
Bellini R and Reek JNH
Chemistry?A European Journal , 18(23), 7091-7099 (2012)
Supramolecular hybrid bidentate ligands in asymmetric hydrogenation
Bellini R and Reek JNH
European Journal of Inorganic Chemistry, 2012(29), 4684-4693 (2012)
Supramolecular control of ligand coordination and implications in hydroformylation reactions
Bellini R, et al.
Angewandte Chemie (International ed. in English), 123(32), 7480-7483 (2011)
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