541753
3,4-Dichloroiodobenzene
98%
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About This Item
Linear Formula:
Cl2C6H3I
CAS Number:
Molecular Weight:
272.90
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
243-874-0
MDL number:
Product Name
3,4-Dichloroiodobenzene, 98%
InChI key
NADPFZNWCQIJJW-UHFFFAOYSA-N
InChI
1S/C6H3Cl2I/c7-5-2-1-4(9)3-6(5)8/h1-3H
SMILES string
Clc1ccc(I)cc1Cl
assay
98%
mp
27-29 °C (lit.)
functional group
chloro
iodo
Quality Level
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Application
3,4-Dichloroiodobenzene may be used in the preparation of:
- tetrachloromethoxybiphenyls
- 1-(3,4-dichlorophenyl)-2-trimethylsilylacetylene
- 2-(3,4-dichlorocinnamyl)isoindoline-1,3-dione
General description
3,4-Dichloroiodobenzene undergoes Stille coupling reaction with vinyltributyltin in the presence of Pd(0)precursors to furnish styrene derivative.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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Synthesis and properties of various poly (diphenylacetylenes) containing tert-amine moieties.
Katsumata T, et al.
Polymer, 49(12), 2808-2816 (2008)
Identification of chlorinated methoxybiphenyls as contaminants in fish and as potential interferences in the determination of chlorinated dibenzo-p-dioxins.
D W Phillipson et al.
Analytical chemistry, 52(14), 2328-2332 (1980-12-01)
Leonardo S Santos et al.
The Journal of organic chemistry, 72(15), 5809-5812 (2007-06-26)
On-line monitoring of Stille reactions was performed via direct infusion electrospray ionization mass spectrometry (ESI-MS) and its tandem version (ESI-MS/MS). When operated in the positive ion mode, ESI(+)-MS was able to transfer, directly from solution to the gas phase, the
Cara A Mosley et al.
Bioorganic & medicinal chemistry, 17(17), 6463-6480 (2009-08-04)
The synthesis and structure-activity relationship analysis of a novel class of amide-based biaryl NR2B-selective NMDA receptor antagonists are presented. Some of the studied compounds are potent, selective, non-competitive, and voltage-independent antagonists of NR2B-containing NMDA receptors. Like the founding member of
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