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Merck
CN

54340

2-Hydroxyethylhydrazine

≥95% (GC)

Synonym(s):

2-Hydrazinoethanol

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About This Item

Linear Formula:
HOCH2CH2NHNH2
CAS Number:
109-84-2
Molecular Weight:
76.10
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
57651467
EC Number:
203-711-6
Beilstein/REAXYS Number:
1731669
MDL number:
MFCD00007623

Key Documents

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Product Name

2-Hydroxyethylhydrazine, ≥95% (GC)

InChI key

GBHCABUWWQUMAJ-UHFFFAOYSA-N

InChI

1S/C2H8N2O/c3-4-1-2-5/h4-5H,1-3H2

SMILES string

NNCCO

assay

≥95% (GC)

refractive index

n20/D 1.493 (lit.)
n20/D 1.493

bp

155-160 °C/32 mmHg (lit.)

mp

−70 °C (lit.)

density

1.123 g/mL at 25 °C (lit.)

functional group

amine
hydrazine
hydroxyl

Quality Level

100

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General description

2-Hydroxyethylhydrazine reacts with β-diketones having strong electron-withdrawing substituents to yield 5-hydroxy-4,5-dihydropyrazoles.

Other Notes

Sales restrictions may apply

pictograms

Skull and crossbonesHealth hazard
GHS06,GHS08

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

170.6 °F - closed cup

flash_point_c

77 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCCN1955
BCCJ4411
BCCC7679
BCBW3137
BCBW0389

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Solvent-free synthesis of 3, 5-di-tert-butylpyrazole and 3, 5-di-substituted-butylpyrazol-1-ylethanol.
Van Wyk JL, et al.
J. Chem. Res. (M), 26(8), 474-477 (2012)
A new method for the synthesis of 1, 4, 5-oxadiazocines and its application in the structure modification of natural products.
Liu W, et al.
Tetrahedron Letters, 46(46), 8009-8012 (2005)
Smaail Radi et al.
Molecules (Basel, Switzerland), 21(8), doi:10-doi:10 (2016-08-17)
A pyridylpyrazole bearing a hydroxyethyl substituent group has been synthesized by condensation of (Z)-4-hydroxy-4-(pyridin-2-yl)but-3-en-2-one with 2-hydroxyethylhydrazine. The compound was well characterized and its structure confirmed by single crystal X-ray diffraction. Density functional calculations have been performed using DFT method with
Reaction of 2-hydroxyethylhydrazine with a trifluoromethyl-?-diketone: Study and structural characterization of a new 5-hydroxy-5-trifluoromethyl-4, 5-dihydropyrazole intermediate.
Montoya V, et al.
Journal of Fluorine Chemistry, 128(9), 1007-1011 (2007)
C Andriamampandry et al.
Journal of neurochemistry, 56(6), 1845-1850 (1991-06-01)
The sequential methylation of ethanolamine and its phosphorylated derivatives has been studied with chick neurons in culture in the presence of several pharmacological agents. Incubation with [3H]ethanolamine in the presence of monomethylethanolamine and dimethylethanolamine indicated that in these neurons the
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