544485
2-Bromo-4-chloroaniline
98%
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About This Item
Linear Formula:
BrC6H3(Cl)NH2
CAS Number:
Molecular Weight:
206.47
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Assay
98%
mp
64-68 °C (lit.)
SMILES string
Nc1ccc(Cl)cc1Br
InChI
1S/C6H5BrClN/c7-5-3-4(8)1-2-6(5)9/h1-3H,9H2
InChI key
SYTBIFURTZACKR-UHFFFAOYSA-N
General description
2-Bromo-4-chloroaniline is a 2-bromo-4-substituted aniline that can be prepared from 4-chloroaniline via electrophilic bromination.
Application
2-Bromo-4-chloroaniline may be used in the preparation of:
- 2-bromo-4-chloro-N-tosylaniline
- 2-bromo-4-chlorothiophenol
- 7-chloro-4a-methyl-4,4a,9,9a-tetrahydro-1H-carbazol-2(3H)-one
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Palladium-Catalyzed ?-Arylation of ?, ?-Unsaturated Ketones: Application to a One-Pot Synthesis of Tricyclic Indolines.
Hyde AM and Buchwald SL.
Angewandte Chemie (Weinheim an der Bergstrasse, Germany), 120(1), 183?186-183?186 (2007)
Synthesis of 2-Aza-and 8-Chloro-2-aza-phenothiazine1.
Saggiomo AJ, et al.
The Journal of Organic Chemistry, 23(12), 1906-1909 (1958)
Palladium-catalyzed coupling of 2-bromoanilines with vinylstannanes. A regiocontrolled synthesis of substituted indoles.
Krolski ME, et al.
The Journal of Organic Chemistry, 53(6), 1170-1176 (1988)
An intriguing effect of lithium perchlorate dispersed on silica gel in the bromination of aromatic compounds by N-bromosuccinimide.
Bagheri M, et al.
Canadian Journal of Chemistry, 83(2), 146-149 (2005)
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