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Merck
CN

546585

Sigma-Aldrich

Poly(9,9-dioctylfluorenyl-2,7-yleneethynylene)

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About This Item

CAS Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23
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mp

>330 °C (lit.)

solubility

chloroform: soluble

fluorescence

λex 387 nm; λem 420 nm in chloroform

SMILES string

CCCCCCCCC1(CCCCCCCC)c2cc(ccc2-c3ccc(cc13)C#C)C#C.CCCCCCCCC4(CCCCCCCC)c5cc(ccc5-c6ccc(cc46)C#CC)C#C

General description

Poly(9,9-dioctylfluorenyl-2,7-yleneethynylene) (PFE) is a conjugating polymer that is a derivative of poly(fluoreneethynylene). It has high chemical stability with blue photo and electroluminescent properties which can be used in organic electronics.

Application

Conducting polymer.
Exhibits blue photo- and electroluminescence.
PFE is a conducting polymer which can be used in the fabrication of non-linear devices such as logic devices, modulators, and optical switches. It may also be used in the formation of polymeric hybrids for ultraviolet photo-detector applications.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Resonant third-order optical nonlinearities of chloroform solution and neat film of poly (9, 9-dioctylfluorenyl-2, 7-yleneethynylene)
Jin Z, et al.
Japanese Journal of Applied Physics, 45(8R), 6263-6263 (2006)
Macromolecules, 33, 3961-3961 (2000)
Poly (fluorenyleneethynylene) s by alkyne metathesis: Optical properties and aggregation behavior
Pschirer NG and Bunz UHF
Macromolecules, 33(11), 3961-3963 (2000)
Macromolecules, 33, 3961-3961 (2000)
Conventional and Inverted UV-PDs Based on Solution Processed PFE: ZnO Active Layer
Memisoglu G and Varlikli C
IEEE Photonics Technology Letters, 27(5), 537-540 (2015)

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