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Merck
CN

547778

Tris[N,N-bis(trimethylsilyl)amide]lanthanum(III)

98%

Synonym(s):

Lanthanum bis(trimethylsilyl)amide, Lanthanum tris(bis(trimethylsilyl)amide)

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About This Item

Linear Formula:
La(N(Si(CH3)3)2)3
CAS Number:
175923-07-6
Molecular Weight:
620.06
NACRES:
NA.22
PubChem Substance ID:
24878978
UNSPSC Code:
12352300
MDL number:
MFCD00271009

Key Documents

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InChI

1S/3C6H18NSi2.La/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3

SMILES string

C[Si](C)(C)N([La](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C

InChI key

ZDYNTRMQDURVDM-UHFFFAOYSA-N

assay

98%

form

solid

reaction suitability

core: lanthanum, reagent type: catalyst

mp

149-153 °C (lit.)

pictograms

FlameCorrosion
GHS02,GHS05

signalword

Danger

Hazard Classifications

Flam. Sol. 1 - Skin Corr. 1B - Water-react 2

supp_hazards

EUH014

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

36.0 °F - closed cup

flash_point_c

2.2 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKCR2470
MKCP3620
MKCP2434
MKCM4996
MKCK7520

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Xiaoyan Tang et al.
Nature communications, 9(1), 2345-2345 (2018-06-13)
Bacterial poly(3-hydroxybutyrate) (P3HB) is a perfectly isotactic, crystalline material possessing properties suitable for substituting petroleum plastics, but high costs and low volumes of its production are impractical for commodity applications. The chemical synthesis of P3HB via ring-opening polymerization (ROP) of

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