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About This Item
Linear Formula:
Gd(N(Si(CH3)3)2)3
CAS Number:
Molecular Weight:
638.40
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23
Assay
98%
form
solid
reaction suitability
core: gadolinium
reagent type: catalyst
mp
67-90 °C (lit.)
SMILES string
C[Si](C)(C)N([Gd](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C
InChI
1S/3C6H18NSi2.Gd/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3
InChI key
LFWPRLGQJJEPDP-UHFFFAOYSA-N
General description
Atomic number of base material: 64 Gadolinium
Application
In many asymmetric catalysis applications, glove box and Schlenk techniques should be employed to prevent exposure of the rare earth catalyst to air and moisture, which can be detrimental to the reaction outcome. Solutions of the catalyst should be made using anhydrous solvents and used shortly after preparation.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Flam. Sol. 1 - Skin Corr. 1B - Water-react 2
Supplementary Hazards
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
Flash Point(F)
36.0 °F - closed cup
Flash Point(C)
2.2 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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