550051
N,N-Dimethylisopropylamine
≥99%
Synonym(s):
DMIPA
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About This Item
Linear Formula:
(CH3)2CHN(CH3)2
CAS Number:
Molecular Weight:
87.16
Beilstein:
1696929
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Quality Level
Assay
≥99%
refractive index
n20/D 1.3905 (lit.)
bp
65.5 °C/752 mmHg (lit.)
density
0.715 g/mL at 25 °C (lit.)
functional group
amine
SMILES string
CC(C)N(C)C
InChI
1S/C5H13N/c1-5(2)6(3)4/h5H,1-4H3
InChI key
VMOWKUTXPNPTEN-UHFFFAOYSA-N
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General description
N,N-Dimethylisopropylamine (DMIPA) is an acyclic tertiary amine. The protonation of DMIPA lead to the efficient migration of its methyl group to other nitrogen-containing compounds in the gas phase.
N,N-Dimethylisopropylamine may be used as an alkylating agent in the preparation of N-methylaniline via palladium catalyzed N-methylation of aniline under microwave condition. It may also be used to prepare a hypergolic ionic liquid by reacting with hydrazoic acid.
Legal Information
Product of Arkema Inc.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 2
Flash Point(F)
-12.6 °F - closed cup
Flash Point(C)
-24.8 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Microwave-Promoted Selective Mono-N-Alkylation of Anilines with Tertiary Amines by Heterogeneous Catalysis.
Lubinu MC, et al.
Chemistry (Weinheim An Der Bergstrasse, Germany), 17(1), 82-85 (2011)
Mert O Karataş et al.
Chemistry & biodiversity, 17(9), e2000258-e2000258 (2020-07-09)
In the present study, coumarin-bearing three pyridinium and three tetra-alkyl ammonium salts were synthesized. The compounds were fully characterized by 1 H- and 13 C-NMR, LC/MS and IR spectroscopic methods and elemental analyses. The cytotoxic properties of all compounds were
Ionic liquids as hypergolic fuels.
Zhang Y, et al.
Angewandte Chemie (International Edition in English), 50(41), 9554-9562 (2011)
Wilson Beita-Sandí et al.
Water research, 170, 115323-115323 (2019-12-04)
In this work, we investigated the effect of bromide ion (Br-) on NDMA formation using model precursor compounds, wastewater effluents and surface waters. Previous studies showed that Br- reacts with chloramines and forms bromochloramine, a reactive compound responsible for NDMA
Shixiang Li et al.
Journal of environmental sciences (China), 58, 331-339 (2017-08-05)
N-nitrosodimethylamine (NDMA) precursors consist of a positively charged dimethylamine group and a non-polar moiety, which inspired us to develop a targeted cation exchange technology to remove NDMA precursors. In this study, we tested the removal of two representative NDMA precursors
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