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Merck
CN

550051

N,N-Dimethylisopropylamine

≥99%

Synonym(s):

DMIPA

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About This Item

Linear Formula:
(CH3)2CHN(CH3)2
CAS Number:
996-35-0
Molecular Weight:
87.16
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24879089
EC Number:
213-635-5
Beilstein/REAXYS Number:
1696929
MDL number:
MFCD00015014
Assay:
≥99%

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InChI key

VMOWKUTXPNPTEN-UHFFFAOYSA-N

InChI

1S/C5H13N/c1-5(2)6(3)4/h5H,1-4H3

SMILES string

CC(C)N(C)C

assay

≥99%

refractive index

n20/D 1.3905 (lit.)

bp

65.5 °C/752 mmHg (lit.)

density

0.715 g/mL at 25 °C (lit.)

functional group

amine

Quality Level

100

Related Categories

General description

N,N-Dimethylisopropylamine (DMIPA) is an acyclic tertiary amine. The protonation of DMIPA lead to the efficient migration of its methyl group to other nitrogen-containing compounds in the gas phase.
N,N-Dimethylisopropylamine may be used as an alkylating agent in the preparation of N-methylaniline via palladium catalyzed N-methylation of aniline under microwave condition. It may also be used to prepare a hypergolic ionic liquid by reacting with hydrazoic acid.

Legal Information

Product of Arkema Inc.

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Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

-12.6 °F - closed cup

flash_point_c

-24.8 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKCK0111
SHBF5444V
06004MC
01505JO

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Microwave-Promoted Selective Mono-N-Alkylation of Anilines with Tertiary Amines by Heterogeneous Catalysis.
Lubinu MC, et al.
Chemistry (Weinheim An Der Bergstrasse, Germany), 17(1), 82-85 (2011)
Mert O Karataş et al.
Chemistry & biodiversity, 17(9), e2000258-e2000258 (2020-07-09)
In the present study, coumarin-bearing three pyridinium and three tetra-alkyl ammonium salts were synthesized. The compounds were fully characterized by 1 H- and 13 C-NMR, LC/MS and IR spectroscopic methods and elemental analyses. The cytotoxic properties of all compounds were
Ionic liquids as hypergolic fuels.
Zhang Y, et al.
Angewandte Chemie (International Edition in English), 50(41), 9554-9562 (2011)
Wilson Beita-Sandí et al.
Water research, 170, 115323-115323 (2019-12-04)
In this work, we investigated the effect of bromide ion (Br-) on NDMA formation using model precursor compounds, wastewater effluents and surface waters. Previous studies showed that Br- reacts with chloramines and forms bromochloramine, a reactive compound responsible for NDMA
Xiang Zhang et al.
Journal of mass spectrometry : JMS, 42(2), 218-224 (2006-12-19)
The methyl migration between the protonated N,N-dimethylisopropylamine and other neutral aliphatic amines in the gas phase has been investigated by a hybrid external chemical ionization source ion trap mass spectrometer. Similar reactions have been found in the aqueous solution by
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