551198
1-(4-Methylphenyl)-3-buten-1-ol
97%
Synonym(s):
1-p-Tolyl-but-3-en-1-ol
Sign In to View Organizational & Contract Pricing
Select a Size
About This Item
Linear Formula:
CH3C6H4CH(OH)CH2CH=CH2
CAS Number:
Molecular Weight:
162.23
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Assay
97%
refractive index
n20/D 1.5270 (lit.)
bp
253 °C (lit.)
density
0.983 g/mL at 25 °C (lit.)
SMILES string
Cc1ccc(cc1)C(O)CC=C
InChI
1S/C11H14O/c1-3-4-11(12)10-7-5-9(2)6-8-10/h3,5-8,11-12H,1,4H2,2H3
InChI key
RCKGDEZXTBRGHR-UHFFFAOYSA-N
General description
1-(4-Methylphenyl)-3-buten-1-ol (1-p-tolyl-but-3-en-1-ol) is a homoallylic alcohol derivative. It can be prepared by the allylation of 4-methylbenzaldehyde using potassium allyltrifluoroborate in the presence of 18-crown-6. It can undergo Prins cyclization with in the presence of cellulose-sulfonic acid to form the corresponding tetrahydropyran-4-ol.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
新产品
This item has
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Cellulose-SO3H as a recyclable catalyst for the synthesis of tetrahydropyranols via Prins cyclization.
Reddy BVS, et al.
Tetrahedron Letters, 51(50), 6511-6515 (2010)
Fernanda C G Barbosa et al.
Molecules (Basel, Switzerland), 17(12), 14099-14110 (2012-11-30)
An efficient method for the allylation of aldehydes containing a broad range of functional groups using potassium allyltrifluoroborate is described. The reaction utilizes a catalytic amount of 18-C-6 in biphasic media under open atmosphere and room temperature to provide the
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service