553387
2-Bromo-5-methoxybenzyl bromide
97%
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About This Item
Linear Formula:
BrC6H3(CH2Br)OCH3
CAS Number:
Molecular Weight:
279.96
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
Product Name
2-Bromo-5-methoxybenzyl bromide, 97%
InChI
1S/C8H8Br2O/c1-11-7-2-3-8(10)6(4-7)5-9/h2-4H,5H2,1H3
SMILES string
COc1ccc(Br)c(CBr)c1
InChI key
MURVUTUZSUEIGI-UHFFFAOYSA-N
assay
97%
mp
90-94 °C (lit.)
functional group
bromo
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Application
2-Bromo-5-methoxybenzyl bromide may be used to synthesize:
- 4-[(2-bromo-5-methoxybenzyl)oxy]-6-methyl-2H-pyran-2-one
- precursors required for the synthesis of pentacyclic sultams
- 3-(benzylamino)coumarins
- 1,3,5-tribenzylated products
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Regulatory Information
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Palladium mediated bis-and tris-biaryl Heck coupling for the synthesis of heterocycles.
Majumdar KC, et al.
Tetrahedron Letters, 49(21), 3419-3422 (2008)
Synthesis of Polycyclic Sultams by Palladium-Catalyzed Intramolecular Cyclization.
Majumdar KC, et al.
Synthesis, 18, 3127-3135 (2009)
New efficient synthesis of pyrido [2, 3-c] coumarin derivatives by palladium-catalyzed Heck cyclization.
Majumdar KC, et al.
Synthesis, 23, 3647-3652 (2007)
Intramolecular cyclization reaction-Palladium (0)-catalyzed cyclization is more effective than tin hydride mediated reaction.
Majumdar KC, et al.
Canadian Journal of Chemistry, 86(4), 325-332 (2008)
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