553581
6-Bromo-2-hydroxy-3-methoxybenzaldehyde
98%
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About This Item
Linear Formula:
BrC6H2(OH)(OCH3)CHO
CAS Number:
Molecular Weight:
231.04
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
98%
InChI
1S/C8H7BrO3/c1-12-7-3-2-6(9)5(4-10)8(7)11/h2-4,11H,1H3
SMILES string
COc1ccc(Br)c(C=O)c1O
InChI key
JUPJZUTYDWXZAQ-UHFFFAOYSA-N
assay
98%
mp
102-105 °C (lit.)
General description
6-Bromo-2-hydroxy-3-methoxybenzaldehyde is a bromobenzaldehyde derivative. It participates in the synthesis of (±)-norannuradhapurine. Its crystals exhibit monoclinic crystal system and space group P21/n.
Application
6-Bromo-2-hydroxy-3-methoxybenzaldehyde may be used in the synthesis of:
- 2-benzyloxy-6-bromo-3-methoxybenzaldehyde
- biphenyls
- antihypertensive natural products S-(+)-XJP and R-(-)-XJP
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Total synthesis and the biological activities of (?)-norannuradhapurine.
Nimgirawath S, et al.
Molecules (Basel), 14(1), 89-101 (2008)
Synthetic studies on selective adenosine A 2A receptor antagonists: Synthesis and structure-activity relationships of novel benzofuran derivatives
Saku O, et al.
Bioorganic & Medicinal Chemistry Letters, 20(3), 1090-1093 (2010)
First total synthesis of antihypertensive natural products S-(+)-XJP and R-(-)-XJP.
Wang C, et al.
Organic & Biomolecular Chemistry, 12(37), 7338-7344 (2014)
Synthesis of NK109, an anticancer benzo [c] phenanthridine alkaloid.
Nakanishi T, et al.
The Journal of Organic Chemistry, 63(13), 4235-4239 (1998)
The conformation of some ortho-bromoarylaldehydes.
Hanson JR, et al.
J. Chem. Res. (M), 7, 416-418 (2008)
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