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555142

1-Diphenylphosphino-1′-(di-tert-butylphosphino)ferrocene

solid

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About This Item

Empirical Formula (Hill Notation):
C30H36FeP2
CAS Number:
95408-38-1
Molecular Weight:
514.40
UNSPSC Code:
12352005
PubChem Substance ID:
24879174
NACRES:
NA.22
MDL number:
MFCD03701526
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Product Name

1-Diphenylphosphino-1′-(di-tert-butylphosphino)ferrocene,

form

solid

Quality Segment

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Coupling Reactions

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

75-79 °C (lit.)

functional group

phosphine

greener alternative category

SMILES string

[Fe].CC(C)(C)P([C]1[CH][CH][CH][CH]1)C(C)(C)C.[CH]2[CH][CH][C]([CH]2)P(c3ccccc3)c4ccccc4

InChI

1S/C17H14P.C13H22P.Fe/c1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;/h1-14H;7-10H,1-6H3;

InChI key

GQIMIFFIUZZVMJ-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. It is an unsymmetric diphosphine ligand for asymmetric catalysis, combining different phosphine environments to provide enhanced selectivity in metal-catalyzed reactions. Click here for more information.

Application

  • Catalyst in microwave-assisted preparation of aryl-alkyl ethers via palladium-catalyzed Hiyama coupling of alkoxysilanes with aryl bromides or aryl chlorides
  • Ligand for catalytic isomerization of methylbutenenitrile via nickel systems
  • Ligand for ruthenium alkylidene complexes for catalysis of metathesis reactions and catalytic norbornene polymerization

Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

Eyeshields, Gloves, type N95 (US)

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