558001
2-Chlorothioanisole
96%
Synonym(s):
2-Chlorophenyl methyl sulfide
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About This Item
Linear Formula:
ClC6H4SCH3
CAS Number:
Molecular Weight:
158.65
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
96%
assay
96%
refractive index
n20/D 1.608 (lit.)
bp
239-240 °C (lit.)
functional group
chloro, thioether
SMILES string
CSc1ccccc1Cl
InChI
1S/C7H7ClS/c1-9-7-5-3-2-4-6(7)8/h2-5H,1H3
InChI key
IHLDFHCSSCVPQW-UHFFFAOYSA-N
General description
2-Chlorothioanisole can be prepared from the reaction between N,N-dimethylformamide, 1,2-dichlorobenzene, finely ground KOH and methyl mercaptan. Benzene dipole moment value analysis of 2-chlorothioanisole indicates that it exists predominantly in trans- form. 1H NMR spectrum of 2-chlorothioanisole has been studied in acetone-d6 solution.
Application
2-Chlorothioanisole may be used to synthesize 2-chlorophenyl methyl sulfone.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
158.0 °F - closed cup
flash_point_c
70 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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The preferred conformations of 2, 4-dichlorophenol, 2, 4-dichloroanisole and their sulphur analogues.
Lumbroso H, et al.
Journal of Molecular Structure, 43(1), 87-95 (1978)
Development of the Large-Scale Preparation of 2-(Methanesulfonyl) benzenesulfonyl Chloride.
Meckler H and Herr RJ.
Organic Process Research & Development, 16(4), 550-555 (2012)
Analysis of chlorophenylmethylsulfides in the urine of rats injected with chlorobenzene by high performance liquid chromatography.
M Yoshida et al.
Industrial health, 23(4), 283-287 (1985-01-01)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 558001-5G | 04061837255786 |