558605
3,5-Difluoroiodobenzene
97%
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About This Item
Linear Formula:
F2C6H3I
CAS Number:
Molecular Weight:
239.99
UNSPSC Code:
12352100
PubChem Substance ID:
MDL number:
InChI
1S/C6H3F2I/c7-4-1-5(8)3-6(9)2-4/h1-3H
SMILES string
Fc1cc(F)cc(I)c1
InChI key
QQCFOQNFPIAENW-UHFFFAOYSA-N
assay
97%
refractive index
n20/D 1.5540 (lit.)
bp
173-174 °C (lit.)
General description
3,5-Difluoroiodobenzene is an asymmetric top molecule. 3,5-Difluoroiodobenzene reacts with magnesium turnings in the presence of a minimum amount of ether to afford the corresponding Grignard reagent. This reagent is employed in the synthesis of tris(3,5-difluorophenyl)methanol.
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
180.0 °F - closed cup
flash_point_c
82.2 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Regulatory Information
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Benzene solvent induced shifts of the proton magnetic resonance spectra of some benzene derivatives. Importance of charge effects.
Wasylishen R, et al.
Canadian Journal of Chemistry, 48(18), 2885-2895 (1970)
Controlling the rotation of asymmetric top molecules by the combination of a long and a short laser pulse.
Viftrup SS, et al.
Physical Review A: General Physics, 79(2), 023404-023404 (2009)
Perfluoroaromatics. Tris (polyfluoroaryl) carbocations.
Kulkarni SV, et al.
Journal of the American Chemical Society, 95(6), 1859-1864 (1973)
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