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Merck
CN

559318

1-(2-Bromoethyl)naphthalene

97%

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About This Item

Empirical Formula (Hill Notation):
C12H11Br
CAS Number:
13686-49-2
Molecular Weight:
235.12
NACRES:
NA.22
PubChem Substance ID:
24879815
UNSPSC Code:
12352100
MDL number:
MFCD00037737

Key Documents

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Product Name

1-(2-Bromoethyl)naphthalene, 97%

InChI

1S/C12H11Br/c13-9-8-11-6-3-5-10-4-1-2-7-12(10)11/h1-7H,8-9H2

SMILES string

BrCCc1cccc2ccccc12

InChI key

GPHCPUFIWQJZOI-UHFFFAOYSA-N

assay

97%

refractive index

n20/D 1.638 (lit.)

bp

237-238 °C/760 mmHg (lit.)

density

1.646 g/mL at 25 °C (lit.)

functional group

bromo

Quality Level

100

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Application

1-(2-Bromoethyl)naphthalene may be used to synthesize 2-iodo-1-[2-(1-naphthyl)ethyl]-1H-benzimidazole.

General description

1-(2-Bromoethyl)naphthalene can be obtained from the reaction between 1-(2-hydroxyethyl)naphthalene and phosphorus tribromide.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
MKCQ6648
MKBT2001V
MKBL0468V
MKBH4927V
MKBF2744

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Potentially carcinogenic cyclopenta [a] phenanthrenes. Part IV. Synthesis of 17-ketones by the Stobbe condensation.
Coombs MM, et al.
J. Chem. Soc. Sect. C, 9, 1266-1271 (1970)
Access to aromatic ring-fused benzimidazoles using photochemical substitutions of the benzimidazol-2-yl radical.
O'Connell JM, et al.
Synthesis, 44(12), 3371-3377 (2012)

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