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Merck
CN

560855

10-Bromo-1-decene

97%

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About This Item

Linear Formula:
Br(CH2)8CH=CH2
CAS Number:
62871-09-4
Molecular Weight:
219.16
NACRES:
NA.22
PubChem Substance ID:
24879896
UNSPSC Code:
12352100
MDL number:
MFCD00078660

Key Documents

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Product Name

10-Bromo-1-decene, 97%

Quality Level

100

InChI

1S/C10H19Br/c1-2-3-4-5-6-7-8-9-10-11/h2H,1,3-10H2

SMILES string

BrCCCCCCCCC=C

InChI key

JVVPJOMYWVYPOF-UHFFFAOYSA-N

assay

97%

refractive index

n20/D 1.4660 (lit.)

bp

50 °C/0.3 mmHg (lit.)

density

1.092 g/mL at 25 °C (lit.)

functional group

alkyl halide
allyl
bromo

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General description

10-Bromo-1-decene can be synthesized by reacting 9-decen-1-ol with PBr3. The product undergoes reduction reaction with 2-propylbenzo[d][1,3,2]dioxaborole (PBD) and Bu3SnH under room temperature conditions to yield 1-decene.

Packaging

10-Bromo-1-decene may be used to synthesize:
  • 4′-(9-decenyloxy) biphenyl-4-carboxylic acid methyl ester
  • 4′-(9-decenyloxy)biphenyl-4-carboxylic acid
  • 9-decenylmagnesium bromide, which was employed for the preparation of (R)-tridec-12-en-2-ol

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

206.0 °F - closed cup

flash_point_c

96.67 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKCN5841
MKCB9344
MKBZ8263V
MKBW2535V
MKBR6624V

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Radical initiation using borole derivatives.
Montgomery I, et al.
Tetrahedron Letters, 49(4), 628-630 (2008)
Room temperature ferroelectric terpolymers with large spontaneous polarization.
Naciri J, et al.
Macromolecules, 28(15), 5274-5279 (1995)
Julian Gebauer et al.
The Journal of organic chemistry, 71(5), 2021-2025 (2006-02-25)
A simple access to gamma,delta-unsaturated-beta-keto lactones is presented, allowing a rapid total synthesis of the naturally occurring 16-membered macrolide antibiotic (-)-A26771B via cross metathesis, asymmetric dihydroxylation, and lactonization as the key steps.
The four-membered-ring chemical shift anomaly.
Lambert JB, et al.
The Journal of Organic Chemistry, 48(22), 3982-3985 (1983)
Novel ferroelectric and electroclinic organosiloxane liquid crystals.
Naciri J, et al.
Chemistry of Materials, 7(7), 1397-1402 (1995)

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