561452
Ethyllithium solution
0.5 M in benzene: cyclohexane
Synonym(s):
Ethyllithium
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About This Item
Linear Formula:
CH3CH2Li
CAS Number:
Molecular Weight:
36.00
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587196
Product Name
Ethyllithium solution, 0.5 M in benzene: cyclohexane
InChI
1S/C2H5.Li/c1-2;/h1H2,2H3;
SMILES string
[Li]CC
InChI key
BLHLJVCOVBYQQS-UHFFFAOYSA-N
concentration
0.5 M in benzene: cyclohexane
density
0.862 g/mL at 25 °C
storage temp.
2-8°C
Quality Level
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Application
Ethyllithium is a general organolithium reagent used in the nucleophilic addition reaction to synthesize a variety of intermediates.
Packaging
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
flash_point_f
-17.0 °F - closed cup
flash_point_c
-27.22 °C - closed cup
Regulatory Information
危险化学品
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Interaction of alkyllithium compounds with base. Complex formation between ethyllithium and triethylamine in benzene.
Brown T L, et al.
Journal of the American Chemical Society, 86(11), 2135-2141 (1964)
Conversions of osmabenzyne and isoosmabenzene.
Zhao Q, et al.
Chemistry?A European Journal , 18(37), 11597-11603 (2012)
Highly stereoselective epoxidation of O-protected 3-hydroxy-1-nitroalkenes.
Jain A, et al.
Tetrahedron, 65(40), 8362-8366 (2009)
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