561665
3-Fluorophenylmagnesium bromide solution
0.5 M in THF
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About This Item
Linear Formula:
FC6H4MgBr
CAS Number:
Molecular Weight:
199.30
UNSPSC Code:
12352103
MDL number:
NACRES:
NA.22
PubChem Substance ID:
reaction suitability
reaction type: Grignard Reaction
concentration
0.5 M in THF
bp
65 °C
density
0.936 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
Fc1cccc([Mg]Br)c1
InChI
1S/C6H4F.BrH.Mg/c7-6-4-2-1-3-5-6;;/h1-2,4-5H;1H;/q;;+1/p-1
InChI key
VFPDAAQAKDGSHQ-UHFFFAOYSA-M
Application
3-Fluorophenylmagnesium bromide is a Grignard reagent that can be used in:
- The preparation of 4-substituted quinazolines by reacting with 2-methylaminobenzonitriles.
- The synthesis of radiolabeled TrkB/C-targeting kinase inhibitor for positron emission tomography (PET) imaging applications.
- Cu-catalyzed carbometalation of substituted cyclopropenes.
Legal Information
Product of Rieke® Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 1
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Faceshields, Gloves, Goggles
Regulatory Information
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Synthesis of quinazolines via an iron-catalyzed oxidative amination of N-H ketimines
Chen C, et al.
The Journal of Organic Chemistry, 83(4), 2395-2401 (2018)
Facially selective and regioselective carbometalation of cyclopropenes by aryl Grignard reagents
Yan N, et al.
The Journal of Organic Chemistry, 73(2), 563-568 (2008)
A kinome-wide selective radiolabeled TrkB/C inhibitor for in vitro and in vivo neuroimaging: synthesis, preclinical evaluation, and first-in-human
Bernard-Gauthier V, et al.
Journal of medicinal chemistry, 60(16), 6897-6910 (2017)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 561665-50ML | 04061837844249 |