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570540

Sigma-Aldrich

(−)-Menthyl (R)-1-[(R)-α-methylbenzyl]aziridine-2-carboxylate

98%

Synonym(s):

(−)-Menthyl (R)-1-[(R)-α-methylbenzyl]-2-azridinecarboxylate, 1-(1′(R)-α-Methylbenzyl)-aziridine-2(R)-carboxylic acid (−)-menthol ester

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1 G
¥162.12

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1 G
¥162.12

About This Item

Empirical Formula (Hill Notation):
C21H31NO2
CAS Number:
397849-98-8
Molecular Weight:
329.48
MDL number:
MFCD04039902
UNSPSC Code:
12352005
PubChem Substance ID:
24880574

¥162.12

List Price¥540.42Save 70%

In StockDetails

Request a Bulk Order

Assay

98%

optical activity

[α]20/D +10.0 to +14.0°, c = 1 in chloroform

mp

75-79 °C (lit.)

SMILES string

C[C@@H]1CC[C@@H](C(C)C)[C@@H](C1)OC(=O)[C@H]2CN2[C@H](C)c3ccccc3

InChI

1S/C21H31NO2/c1-14(2)18-11-10-15(3)12-20(18)24-21(23)19-13-22(19)16(4)17-8-6-5-7-9-17/h5-9,14-16,18-20H,10-13H2,1-4H3/t15-,16-,18+,19-,20-,22?/m1/s1

InChI key

BLLGOPLLCDRJQD-NIPOPRQDSA-N

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assay

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assay

97%

assay

97%

assay

97%

Quality Level

100

Quality Level

-

Quality Level

100

Quality Level

-

mp

93-97 °C (lit.)

mp

62-66 °C

mp

75-80 °C

mp

52-57 °C

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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    MKBB8322
    06324DA

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    Tandem approach for the synthesis of imidazo [1, 2-a] pyridines from alcohols.
    Ramesha AB, et al.
    Tetrahedron Letters, 54(1), 95-100 (2013)
    Dean Y Maeda et al.
    Journal of medicinal chemistry, 57(20), 8378-8397 (2014-09-26)
    The G protein-coupled chemokine receptors CXCR1 and CXCR2 play key roles in inflammatory diseases and carcinogenesis. In inflammation, they activate and recruit polymorphonuclear cells (PMNs) through binding of the chemokines CXCL1 (CXCR1) and CXCL8 (CXCR1 and CXCR2). Structure-activity studies that
    Syntheses of 2-chloro-and 2-amino-5-fluoropyridines and isolation of a novel difluoroboryl imidate.
    Smakula Hand E and Baker DC.
    Synthesis, 12, 905-908 (1989)
    Synthesis of 2-Amino-5-Fluoropyridine.
    MA ZP, et al.
    Journal of Chemical Engineering of Chinese Universities / Gao Xiao Hua Xue Gong Cheng Xue Bao, 4, 015-015 (2008)
    Russell J Needham et al.
    Journal of inorganic biochemistry, 210, 111154-111154 (2020-08-11)
    Twenty-four novel organometallic osmium(II) phenylazopyridine (AZPY) complexes have been synthesised and characterised; [Os(η6-arene)(5-RO-AZPY)X]Y, where arene = p-cym or bip, AZPY is functionalized with an alkoxyl (O-R, R = Me, Et, nPr, iPr, nBu) or glycolic (O-{CH2CH2O}nR*, n = 1-4, R* = H, Me, or Et) substituent on the

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