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Merck
CN

57110

Indium(III) chloride hydrate

~39% indium basis, 2-3 mol/mol water

Synonym(s):

Trichloroindium, indium trichloride

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About This Item

Linear Formula:
InCl3 · aq
CAS Number:
10025-82-8
Molecular Weight:
221.18 (anhydrous basis)
NACRES:
NA.22
PubChem Substance ID:
57651618
UNSPSC Code:
12352300
EC Number:
233-043-0
MDL number:
MFCD00149744

Key Documents

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InChI key

KYCHGXYBBUEKJK-UHFFFAOYSA-K

InChI

1S/3ClH.In.H2O/h3*1H;;1H2/q;;;+3;/p-3

SMILES string

O.Cl[In](Cl)Cl

reaction suitability

core: indium, reagent type: catalyst

concentration

~39% In

impurities

2-3 mol/mol water

Application

Reagent/catalyst for various organic transformations, e.g. allylation of aldehydes, ketones, and quinones; Diels-Alder reaction; the aldol reaction; Michael additions; the reductive Friedel-Crafts;

pictograms

Health hazardCorrosion
GHS08,GHS05

signalword

Danger

Hazard Classifications

Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1C - STOT RE 1 Inhalation

target_organs

Lungs

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
BCBH4279V
BCBG4642V
BCBH9936V
BCBF7754V
BCBD8055V

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Chapman, C. J.; Frost, C. G. et al.
Tetrahedron Letters, 42, 773-773 (2001)
S Kobayashi et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 6(19), 3491-3494 (2000-11-10)
Group 3-15 metal chlorides (Lewis acids) were classified on the basis of activity and aldehyde- and aldimine-selectivity in an addition reaction of a silyl enol ether. Based on the experimental results, metal chlorides (Lewis acids) were classified as follows: A
Loh, T.-P.; Li, X.-R.,
Angewandte Chemie (International Edition in English), 36, 980-980 (1997)
Reddy, B. G.; Kumareswaran, R. et al.
Tetrahedron Letters, 41, 10333-10333 (2000)
Sebastian Bernhardt et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(3), 828-833 (2012-12-21)
Magnesium, indium, palladium: An efficient one-pot procedure for the direct preparation of triorganoindium reagents from organic halides by means of magnesium insertion in the presence of InCl(3) and LiCl is reported (see scheme). The organoindium reagents are obtained in good
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