576689
2-Iodo-4-nitroaniline
97%
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About This Item
Linear Formula:
IC6H3(NO2)NH2
CAS Number:
Molecular Weight:
264.02
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Assay
97%
form
solid
mp
105-109 °C (lit.)
functional group
iodo
nitro
SMILES string
Nc1ccc(cc1I)[N+]([O-])=O
InChI
1S/C6H5IN2O2/c7-5-3-4(9(10)11)1-2-6(5)8/h1-3H,8H2
InChI key
LOLSEMNGXKAZBZ-UHFFFAOYSA-N
General description
2-Iodo-4-nitroaniline can be synthesized via reaction of 4-nitroaniline with iodine and silver acetate.
Application
2-iodo-4-nitroaniline may be used to synthesize the following:
- 2-iodo-4-nitrobenzonitrile via reaction with sodium nitrite to form a diazonium salt, which then reacts with a mixture of CuCN/KCN
- 2-iodo-p-phenylenediamine by reacting with tin(II)dihydrate in conc.HCl
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Tetrahedron Letters, 45(46), 8569-8573 (2004)
"Preparation of 2-arylated-1, 4-phenylenediamines by palladium-catalyzed cross-coupling reactions"
Jensen EA, et al.
Journal of Organometallic Chemistry, 653(01), 122-128 (2002)
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