578703
Dichloro(3-methyl-2-butenylidene)bis(tricyclopentylphosphine)ruthenium(II)
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About This Item
Empirical Formula (Hill Notation):
C35H62Cl2P2Ru
CAS Number:
Molecular Weight:
716.79
UNSPSC Code:
12352300
PubChem Substance ID:
MDL number:
InChI
1S/2C15H27P.C5H8.2ClH.Ru/c2*1-2-8-13(7-1)16(14-9-3-4-10-14)15-11-5-6-12-15;1-4-5(2)3;;;/h2*13-15H,1-12H2;1,4H,2-3H3;2*1H;/q;;;;;+2/p-2
SMILES string
Cl[Ru]Cl.[CH][CH][C](C)C.C1CCC(C1)P(C2CCCC2)C3CCCC3.C4CCC(C4)P(C5CCCC5)C6CCCC6
InChI key
UCDVULRIJNJVEV-UHFFFAOYSA-L
form
solid
mp
94-96 °C (lit.)
storage temp.
2-8°C
Application
Metathesis: Ruthenium-Based Metathesis Catalysts
- Reactant for synthesis of ruthenium olefin metathesis catalysts
- Catalyst for ring-opening metathesis polymerization
Kinetic application profile similar to that of Grubbs 1st Generation Catalyst.
Other Notes
NO BULK ORDERS
Legal Information
US Patent No. 5,969,170 and foreign equivalents apply. Sale of this product conveys to the buyer a limited-use research license. For questions, please contact us at aldrich@sial.com
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Find documentation for the products that you have recently purchased in the Document Library.
Furstner, A.
Angewandte Chemie (International Edition in English), 3012-3012 (2000)
Vougioukalakis, G. C.; Grubbs, R. H.
Chemical Reviews, 1746-1746 (2010)
Schuster, M.; Blechert, S.
Angewandte Chemie (International Edition in English), 2036-2036 (1997)
Grubbs, R. H.
Tetrahedron, 7117-7117 (2004)
Trnka, T. M.; Grubbs, R. H.
Accounts of Chemical Research, 18-18 (2001)
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