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Merck
CN

590231

Di(acetato)dicyclohexylphenylphosphinepalladium(II), polymer-bound FibreCat®

Pd ~5 %, extent of labeling: 0.4-0.6 mmol/g PPH3 ligand content loading

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About This Item

CAS Number:
UNSPSC Code:
12352103
NACRES:
NA.22
MDL number:
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SMILES string

[Pd+2].P(C3CCCCC3)(C2CCCCC2)c1ccccc1.[O-]C(=O)C.[O-]C(=O)C

InChI key

ZMMYBYFXUHUTSH-UHFFFAOYSA-L

product line

FibreCat®

form

solid

composition

Pd, ~5%

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: solution phase peptide synthesis, reagent type: catalyst
reaction type: Coupling Reactions

extent of labeling

0.4-0.6 mmol/g PPH3 ligand content loading

Quality Level

Application

Supported catalyst used in Suzuki coupling of less reactive aryl chloride with boronic acids. This supported catalyst is generally more selective than the free homogeneous catalyst, and palladium leaching is very low (<2 ppm).
The resin can also be recycled.

Legal Information

FibreCat is a registered trademark of Johnson Matthey PLC

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Colacot, T.J.
Organometallics, 21, 3301-3301 (2002)

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