598089
Cyclopentadienyldicarbonyl(tetrahydrofuran)iron(II) tetrafluoroborate
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About This Item
Empirical Formula (Hill Notation):
C11H13BF4FeO3
CAS Number:
Molecular Weight:
335.87
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22
SMILES string
[Fe+].[C-]#[O+].[C-]#[O+].F[B-](F)(F)F.[CH]1[CH][CH][CH][CH]1.C2CCOC2
InChI
1S/C5H5.C4H8O.2CO.BF4.Fe/c2*1-2-4-5-3-1;2*1-2;2-1(3,4)5;/h1-5H;1-4H2;;;;/q;;;;-1;+1
InChI key
UEQAYXWNQGYVGN-UHFFFAOYSA-N
reaction suitability
core: iron, reagent type: catalyst
mp
110 °C (dec.) (lit.)
storage temp.
2-8°C
Application
Catalyst for:
- Preparation of β-keto esters via Lewis acid-catalyzed addition of Et diazoacetate to arylaldehydes
- Iron mediated nitrenoid transfer
- Lewis acid catalyzed aziridination, cyclopropanation, and insertion reaction with diazo compounds
- Diels-Alder reaction of dienes with enones
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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