61930
L-tert-Leucinol hydrochloride
≥99.0% (CHN)
Synonym(s):
(S)-2-Amino-3,3-dimethyl-1-butanol hydrochloride
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About This Item
Empirical Formula (Hill Notation):
C6H15NO · HCl
Molecular Weight:
153.65
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352200
MDL number:
assay
≥99.0% (CHN)
optical activity
[α]20/D +35±1°, c = 1% in H2O
mp
196-198 °C
application(s)
peptide synthesis
SMILES string
Cl[H].CC(C)(C)[C@H](N)CO
InChI
1S/C6H15NO.ClH/c1-6(2,3)5(7)4-8;/h5,8H,4,7H2,1-3H3;1H/t5-;/m1./s1
InChI key
BFBMCXSYQJNKSS-NUBCRITNSA-N
Other Notes
Chiral auxiliary and building block which usually induces higher stereoselectivities than the corresponding derivatives of valinol; e.g. Claisen rearrangement of N-allyl ketene-N,O-acetals; preparation of an effective C2-symmetrical catalyst for hydrosilylation of ketones; alkylation of bicyclic N,O-acetals with keto acids; Ullmann coupling
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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H. Nishiyama et al.
Organometallics, 8, 846-846 (1989)
T.D. Nelson et al.
The Journal of Organic Chemistry, 59, 2655-2655 (1994)
M.J. Kurth et al.
Journal of the American Chemical Society, 107, 443-443 (1985)