631582
(R)-(+)-2,2′-Bis(methoxymethoxy)-1,1′-binaphthalene
97%
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About This Item
Linear Formula:
(CH3OCH2OC10H6)2
CAS Number:
Molecular Weight:
374.43
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
Assay
97%
form
solid
optical activity
[α]20/D +92°, c = 1% in chloroform
mp
101-105 °C (lit.)
SMILES string
COCOc1ccc2ccccc2c1-c3c(OCOC)ccc4ccccc34
InChI
1S/C24H22O4/c1-25-15-27-21-13-11-17-7-3-5-9-19(17)23(21)24-20-10-6-4-8-18(20)12-14-22(24)28-16-26-2/h3-14H,15-16H2,1-2H3
InChI key
YIAQRNNJNMLGTP-UHFFFAOYSA-N
Application
3- or 3,3′-di-substituted products can be obtained easily via ortho-metallation and subsequent treatment with an electrophile to give the corresponding BINOL derivatives.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Cox, P. J. et al
Tetrahedron Letters, 33, 2253-2253 (1992)
Articles
We present an article concerning BINOL and Derivatives.
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