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633089

trans-N,N′-Dimethylcyclohexane-1,2-diamine

Name: trans-N,N′-Dimethylcyclohexane-1,2-diamine
Brand: ALDRICH

97%

Synonym(s):

N,N′-Dimethyl-trans-1,2-cyclohexanediamine, rel-(1R,2R)-N1,N2-Dimethyl-1,2-cyclohexanediamine, trans-1,2-Bis(methylamino)cyclohexane, trans-N,N′-Dimethyl-1,2-cyclohexanediamine, trans-N,N′-Dimethyl-1,2-diaminocyclohexane

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About This Item

Empirical Formula (Hill Notation):

C₈H₁₈N₂

CAS Number:

67579-81-1

Molecular Weight:

142.24

NACRES:

NA.22

PubChem Substance ID:

24882536

UNSPSC Code:

12352100

MDL number:

MFCD03001702

Assay:

97%

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Properties

Quality Level

100

assay

97%

refractive index

n20/D 1.472 (lit.)

bp

78-80 °C/18 mmHg (lit.)

density

0.902 g/mL at 25 °C (lit.)

functional group

amine

SMILES string

CN[C@@H]1CCCC[C@H]1NC

InChI

1S/C8H18N2/c1-9-7-5-3-4-6-8(7)10-2/h7-10H,3-6H2,1-2H3/t7-,8-/m1/s1

InChI key

JRHPOFJADXHYBR-HTQZYQBOSA-N

Description

General description

trans-N,N′-Dimethylcyclohexane-1,2-diamine is a ligand used to promote N-alkenylation and N-alkylation reactions of amides.

Application

trans-N,N′-dimethylcyclohexane-1,2-diamine can be used as a ligand in the synthesis of the following products via copper catalyzed C-N coupling reactions:

vinylsulfoximines obtained from NH sulfoximes and vinyl bromides
N-arylpyridones obtained via reaction between 2-substituted pyridines and aryl halides
N-aryl amines obtained via reaction between amines and aryl iodides/aryl bromides