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Merck
CN

638102

4,4′-Bis(triethoxysilyl)-1,1′-biphenyl

≥90% (VPCC)

Synonym(s):

4,4′-Bis(triethoxysilyl)biphenyl

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About This Item

Linear Formula:
[-C6H4Si(OC2H5)3]2
CAS Number:
123640-93-7
Molecular Weight:
478.73
NACRES:
NA.22
PubChem Substance ID:
24882911
UNSPSC Code:
12352103
MDL number:
MFCD06798075

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Product Name

4,4′-Bis(triethoxysilyl)-1,1′-biphenyl, ≥90% (VPCC)

InChI

1S/C24H38O6Si2/c1-7-25-31(26-8-2,27-9-3)23-17-13-21(14-18-23)22-15-19-24(20-16-22)32(28-10-4,29-11-5)30-12-6/h13-20H,7-12H2,1-6H3

SMILES string

CCO[Si](OCC)(OCC)c1ccc(cc1)-c2ccc(cc2)[Si](OCC)(OCC)OCC

InChI key

KENDGHJJHKCUNB-UHFFFAOYSA-N

assay

≥90% (VPCC)

bp

203-206 °C/0.3 mmHg (lit.)

density

1.047 g/mL at 25 °C (lit.)

Quality Level

100

Related Categories

Application

4,4′-Bis(triethoxysilyl)-1,1′-biphenyl (BTESB) can be used as an indicator to determine the chirality of helical silica nanotubes.

BTESB can also be utilized as a precursor to prepare:
  • Helical 4, 4′-biphenylene-silica nanotubes and nanoribbons using 3-aminopropyltrimethoxysilane as a co-structure-directing agent.
  • Biphenyl-bridged alkoxysilane-based crosslinked polyalkoxysilane by condensation with linear aliphatic diols.
  • Biphenylene-bridged silsesquioxane thin films by the sol-gel method.

A silicon-based nucleophile shown to be reactive in Pd-catalyzed cross-coupling reactions.

hcodes

H413

Hazard Classifications

Aquatic Chronic 4

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

>230.0 °F - closed cup

flash_point_c

> 110 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

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Certificates of Analysis (COA)

Lot/Batch Number
SHBS4342
SHBP7760
SHBM8314
SHBK2476
SHBJ5088

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Preparation of biphenyl-bridged, crosslinked polyalkoxysilanes: Determination of oil/organic solvent absorption features
Kizil S and Bulbul Sonmez H
Journal of Applied Polymer Science, 133(48), 770-772 (2016)
A chirality indicator for the walls and the surfaces of silica nanotubes
Hou F-W, et al.
Chinese Chemical Letters = Zhongguo Hua Xue Kuai Bao, 24(8), 770-772 (2013)
Chimie douce route to novel acoustic waveguides based on biphenylene-bridged silsesquioxanes
Masse P, et al.
Journal of Materials Chemistry, 21(38), 14581-14586 (2011)
Yi Li et al.
Nanotechnology, 22(13), 135605-135605 (2011-02-24)
An anionic gelator, D-C12ValC10COONa, derived from D-valine can cause physical gels in water and organic solvents. Helical 4,4(')-biphenylene-silica nanotubes and nanoribbons were prepared using it with 3-aminopropyltrimethoxysilane as a co-structure-directing agent and 4,4(')-bis(triethoxysilyl)-1,1(')-biphenyl (BTESB) as precursor. It was found that
Lorenzo Abate et al.
Polymers, 11(9) (2019-09-12)
Two series of novel dumbbell-shaped polyhedral oligomeric silsesquioxanes (POSSs), fully functionalized with phenyl groups at the corner of the silicon cages, were used to prepare polystyrene (PS) nanocomposites through the method of in situ polymerization. The percentage of the molecular
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