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Merck
CN

639346

Sigma-Aldrich

tert-Butyldiisopropylphosphine

97%

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About This Item

Empirical Formula (Hill Notation):
C10H23P
CAS Number:
Molecular Weight:
174.26
MDL number:
UNSPSC Code:
12352001
PubChem Substance ID:
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Assay

97%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

bp

77-79 °C/10 mmHg (lit.)

density

0.837 g/mL at 25 °C (lit.)

functional group

phosphine

SMILES string

CC(C)P(C(C)C)C(C)(C)C

InChI

1S/C10H23P/c1-8(2)11(9(3)4)10(5,6)7/h8-9H,1-7H3

InChI key

OLSMQSZDUXXYAY-UHFFFAOYSA-N

General description

tert-Butyldiisopropylphosphine is a phosphine ligand that can be utilized in C-C bond forming reactions.

Application

  • Monodentate P-Donor Ligand
  • Catalyst for selective propylene dimerization to dimethylbutenes

Pictograms

FlameCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

监管及禁止进口产品

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