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Merck
CN

640263

Pentabromobenzyl acrylate

95%

Synonym(s):

2,3,4,5,6-Pentabromobenzyl acrylate

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About This Item

Empirical Formula (Hill Notation):
C10H5Br5O2
CAS Number:
59447-55-1
Molecular Weight:
556.67
NACRES:
NA.23
PubChem Substance ID:
24883084
UNSPSC Code:
12352103
EC Number:
261-767-7
MDL number:
MFCD00804467

Key Documents

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Product Name

Pentabromobenzyl acrylate, 95%

InChI key

GRKDVZMVHOLESV-UHFFFAOYSA-N

InChI

1S/C10H5Br5O2/c1-2-5(16)17-3-4-6(11)8(13)10(15)9(14)7(4)12/h2H,1,3H2

SMILES string

Brc1c(Br)c(Br)c(COC(=O)C=C)c(Br)c1Br

assay

95%

mp

115-116 °C (lit.)

storage temp.

2-8°C

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Application

Pentabromobenzyl acrylate can form copolymers with styrene. Polymerization of the monomer in methyl ethyl ketone can yield novel, flame retardant nano/micro sized (0.06 ± 0.01 and 1.70 ± 0.23 μm) particles. Polyamide (PA6) treated with PMA and montorillonite (OMMT) has been described in a study.

General description

The oxygen index (OI) value of PMA is 29.7.

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H317,H319

Hazard Classifications

Eye Irrit. 2 - Skin Sens. 1

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKCK3781
MKBB3430
11024MB

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Polyamide 6 treated with pentabromobenzyl acrylate and layered silicates.
Lewin M, et al.
Polymers for Advanced Technologies, 21(11), 825-834 (2010)
Light scattering characterization of tetramethyl polycarbonate blends with polystyrene and with styrene?pentabromobenzyl acrylate copolymers
Merfeld GD, et al.
Polymer, 41(2), 649-661 (2000)
Synthesis and characterization of new flame-retardant microspheres by dispersion polymerization of pentabromobenzyl acrylate
Goldshtein J and Margel S
European Polymer Journal, 45(11), 2987-2995 (2009)
Olesya Daikos et al.
Physical chemistry chemical physics : PCCP, 18(47), 32369-32377 (2016-11-18)
Pentabrominated and fluorinated aromatic (meth)acrylates as well as their non-halogenated counterparts have been studied with the aim to avoid conventional photoinitiators and to overcome some negative consequences related to their use. Therefore, RTIR spectroscopy, laser flash photolysis and GC/MS were

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