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Merck
CN

640697

Sigma-Aldrich

(1E,3Z)-1-Methoxy-2-methyl-3-(trimethylsilyloxy)-1,3-pentadiene

Synonym(s):

(1E,3Z)-1-Methoxy-2-methyl-3-[(trimethylsilyl)oxy]-penta-1,3-diene, [(1-(2-Methoxy-1-methylvinyl)propenyloxy]trimethylsilan

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About This Item

Empirical Formula (Hill Notation):
C10H20O2Si
CAS Number:
72486-93-2
Molecular Weight:
200.35
MDL number:
MFCD10567404
UNSPSC Code:
12352100
PubChem Substance ID:
24882659
NACRES:
NA.22

Key Documents

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refractive index

n20/D 1.4650 (lit.)

bp

65 °C/6 mmHg (lit.)

density

0.899 g/mL at 25 °C (lit.)

functional group

ether

storage temp.

2-8°C

SMILES string

CO\C=C(C)\C(O[Si](C)(C)C)=C\C

InChI

1S/C10H20O2Si/c1-7-10(9(2)8-11-3)12-13(4,5)6/h7-8H,1-6H3/b9-8+,10-7-

InChI key

SSGAQVOLXCOJGN-AZRUORMVSA-N

Application

Danishefsky diene used as a reactant for:
Preparation of migrastatin analog as cell migration inhibitor for treatment of tumor metastasis
Preparation of dihydropyridinones by chlorosilane-promoted aza-Diels-Alder addition
Synthesis on non-proteinogenic amino esters via stereoselective Lewis acid-catalyzed aza-Diels-Alder cycloaddition with conjugated (cyclo)dienes

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302

Hazard Classifications

Acute Tox. 4 Oral

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

178.0 °F - closed cup

Flash Point(C)

81.1 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Lot/Batch Number
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