640697
(1E,3Z)-1-Methoxy-2-methyl-3-(trimethylsilyloxy)-1,3-pentadiene
Synonym(s):
(1E,3Z)-1-Methoxy-2-methyl-3-[(trimethylsilyl)oxy]-penta-1,3-diene, [(1-(2-Methoxy-1-methylvinyl)propenyloxy]trimethylsilan
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About This Item
Empirical Formula (Hill Notation):
C10H20O2Si
CAS Number:
Molecular Weight:
200.35
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
refractive index
n20/D 1.4650 (lit.)
bp
65 °C/6 mmHg (lit.)
density
0.899 g/mL at 25 °C (lit.)
functional group
ether
storage temp.
2-8°C
SMILES string
CO\C=C(C)\C(O[Si](C)(C)C)=C\C
InChI
1S/C10H20O2Si/c1-7-10(9(2)8-11-3)12-13(4,5)6/h7-8H,1-6H3/b9-8+,10-7-
InChI key
SSGAQVOLXCOJGN-AZRUORMVSA-N
Application
Danishefsky diene used as a reactant for:
Preparation of migrastatin analog as cell migration inhibitor for treatment of tumor metastasis
Preparation of dihydropyridinones by chlorosilane-promoted aza-Diels-Alder addition
Synthesis on non-proteinogenic amino esters via stereoselective Lewis acid-catalyzed aza-Diels-Alder cycloaddition with conjugated (cyclo)dienes
Preparation of migrastatin analog as cell migration inhibitor for treatment of tumor metastasis
Preparation of dihydropyridinones by chlorosilane-promoted aza-Diels-Alder addition
Synthesis on non-proteinogenic amino esters via stereoselective Lewis acid-catalyzed aza-Diels-Alder cycloaddition with conjugated (cyclo)dienes
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
178.0 °F - closed cup
flash_point_c
81.1 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Global Trade Item Number
| SKU | GTIN |
|---|---|
| 640697-1G | 04061826182703 |