643181
Palladium
extent of labeling: 5 wt. % loading (dry basis), matrix activated carbon, wet support, Degussa type E105CA/W
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About This Item
Linear Formula:
Pd
CAS Number:
Molecular Weight:
106.42
UNSPSC Code:
12141733
PubChem Substance ID:
MDL number:
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
extent of labeling
5 wt. % loading (dry basis)
resistivity
9.96 μΩ-cm, 20°C
matrix
activated carbon, wet support
bp
2970 °C (lit.)
mp
1554 °C (lit.)
density
12.02 g/cm3 (lit.)
SMILES string
[Pd]
InChI
1S/Pd
InChI key
KDLHZDBZIXYQEI-UHFFFAOYSA-N
Application
It can be used along with ligandless palladium on activated carbon in the preparation of 1-biphenyl-4-yl-ethanone via Suzuki-Miyaura cross-coupling of phenylboronic acid with 4-chloro-acetophenone in water.
Catalyst for hydrogenation of alkenes, alkynes, ketones, nitriles,imines, azides, nitro groups, benzenoid and heterocyclic aromatics;used for hydrogenolysis of cyclopropanes, benzyl derivatives,epoxides, hydrazines, and halides; used to dehydrogenate aromatics and deformylate aldehydes.
Heterogeneous catalyst for carbon-carbon coupling reactions (Heck and Suzuki)
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Storage Class
13 - Non Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Suzuki-Miyaura cross-coupling of aryl chlorides in water using ligandless palladium on activated carbon.
Lysen M and Kohler K.
Synlett, 2005(11), 1671-1674 (2005)
V Volarevic et al.
Journal of B.U.ON. : official journal of the Balkan Union of Oncology, 18(1), 131-137 (2013-04-25)
As novel therapeutic agents relevant to colon cancer therapy are explored continuously, we tested 4 R2edda-type ligand precursors O,O'-dialkyl esters of (S,S)-ethylenediamine-N,N'-di-2-(4-methyl)pentanoic acid (L1.2HCl-L4.2HCl) and corresponding palladium(II) and platinum(II) complexes against the human colon cancer cell lines CaCo-2, SW480 and
Ling Li et al.
Nature chemistry, 5(7), 607-612 (2013-06-22)
The development of transition metal-catalysed cross-coupling reactions has greatly influenced the manner in which the synthesis of complex organic molecules is approached. A wide variety of methods are now available for the formation of C(sp(2))-C(sp(2)) bonds, and more recent work
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 643181-10G | 04061833548707 |
| 643181-50G | 04061833548714 |