649074
Tricyclopentylphosphine
97%
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About This Item
InChI key
DHWBYAACHDUFAT-UHFFFAOYSA-N
InChI
1S/C15H27P/c1-2-8-13(7-1)16(14-9-3-4-10-14)15-11-5-6-12-15/h13-15H,1-12H2
SMILES string
C1CCC(C1)P(C2CCCC2)C3CCCC3
assay
97%
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Cross Couplings
density
0.986 g/mL at 20 °C (lit.), 0.979 g/mL at 25 °C
functional group
phosphine
Application
- Nickel-catalyzed cycloaddition of enones and alkynes
- Rhodium-catalyzed allylation of aldehydes with homoallylic alcohols
- Hydrocarbamoylation of alkynes by nickel/Lewis-acid catalysis
- Alkenylation of imidazoles by nickel/Lewis acid catalysis
- Palladium-catalyzed Negishi cross-coupling reactions
- PHosphine-catalyzed synthesis of 6-substituted 2-pyrones
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B
Storage Class
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
410.0 °F - closed cup
flash_point_c
210 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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