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Merck
CN

652407

Tris(2,2′-bipyridyl-d8)ruthenium(II) hexafluorophosphate

95%

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About This Item

Empirical Formula (Hill Notation):
C30D24F12N6P2Ru
CAS Number:
67573-02-8
Molecular Weight:
883.70
UNSPSC Code:
12352103
PubChem Substance ID:
24883881
MDL number:
MFCD07369761

Key Documents

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mass shift

M+24

InChI

1S/3C10H8N2.2F6P.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2*1-7(2,3,4,5)6;/h3*1-8H;;;/q;;;2*-1;+2/i3*1D,2D,3D,4D,5D,6D,7D,8D;;;

SMILES string

[Ru].F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.[2H]c1nc(c([2H])c([2H])c1[2H])-c2nc([2H])c([2H])c([2H])c2[2H].[2H]c3nc(c([2H])c([2H])c3[2H])-c4nc([2H])c([2H])c([2H])c4[2H].[2H]c5nc(c([2H])c([2H])c5[2H])-c6nc([2H])c([2H])c([2H])c6[2H]

InChI key

KLDYQWXVZLHTKT-LUXBKWEBSA-N

assay

95%

reaction suitability

reagent type: catalyst
core: ruthenium

mp

>300 °C (lit.)

General description

Fluorescent dye tris(2,2′-bipyridine)ruthenium has a high quenching coefficient k = 2.6%/oK.

Application

High efficiency triplet emitter for OLED/Sensor research.
The emitting layers can be used as dopants for host materials in organic light emitting diodes and metal organic frameworks used for sensing, storage and catalysis applications.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
14901TC

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Photophysical Characterization of a Ruthenium(II) Tris(2,2?-bipyridine)-Doped Zirconium UiO-67 Metal?Organic Framework.
Maza WA and Morris AJ
The Journal of Physical Chemistry C, 8803-8817 null
Photophysical Characterization of a Ruthenium(II) Tris(2,2?-bipyridine)-Doped Zirconium UiO-67 Metal?Organic Framework.
Maza WA and Morris AJ
The Journal of Physical Chemistry C null
Holographically patterned activation using photo-absorber induced neural?thermal stimulation
Farah N, et al.
Journal of Neural Engineering null
Holographically patterned activation using photo-absorber induced neural?thermal stimulation
Farah N, et al.
Journal of Neural Engineering, 056004 null
Hongki Kang et al.
ACS nano, 14(9), 11406-11419 (2020-09-05)
Thermoplasmonic effect-based neural stimulation has been suggested as an alternative optical neural stimulation technology without genetic modification. Integration of near-infrared light with plasmonic gold nanoparticles has been demonstrated as a neuromodulation tool on in vitro neuronal network models. In order

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