658235
Lithium dimethylaminoborohydride solution
1 M in THF
Synonym(s):
N-Methylmethanamine boron complex, Lithium (dimethylamino)trihydroborate, Lithium trihydro(N-methylmethanaminato)borate
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About This Item
Product Name
Lithium dimethylaminoborohydride solution, 1 M in THF
InChI
1S/C2H9BN.Li/c1-4(2)3;/h1-3H3;/q-1;+1
SMILES string
[Li+].[BH3-]N(C)C
InChI key
CEDUMRZWZLVFKS-UHFFFAOYSA-N
reaction suitability
reagent type: reductant
concentration
1 M in THF
refractive index
n20/D 1.423
density
0.882 g/mL at 25 °C
storage temp.
2-8°C
Quality Level
Related Categories
Application
Reactant for:
- B-H oxidative addition reactions
- Reduction and amination reactions
- Reduction of N-alkyl lactams
- Synthesis of tertiary amine-boranes
General description
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Respiratory system
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
Regulatory Information
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Articles
Lithium aminoborohydride (LAB) reagents are a new class of powerful and selective reagents developed in the laboratory of Professor Bakthan Singaram at the University of California, Santa Cruz.
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