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Merck
CN

658693

Pd(II) EnCat® BINAP30

extent of labeling: 0.39 mmol/g Pd loading, BINAP 0.25, Pd 1.0

Synonym(s):

Palladium acetate and BINAP, microencapsulated in polyurea matrix

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About This Item

UNSPSC Code:
12161600
NACRES:
NA.22
MDL number:
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composition

BINAP, 0.25 , Pd, 1.0

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

extent of labeling

0.39 mmol/g Pd loading

Quality Level

General description

It is Pd EnCat® catalyst, wherein palladium acetate and 1,1′-binaphthalene-2,2′-diylbis(diphenylphosphine) (BINAP) are microencapsulated within a polyurea matrix, which prevents palladium leaching.

Application

Features and Benefits

The advantage of Pd EnCat® catalysts are:
  • Low residual metal levels in crude product.
  • Easy recovery of catalyst.
  • Compatibility of immobilized metal with various ligands to effect C–C bond forming reactions.
  • Safer and easier to handle than Pd/C for hydrogenation.
  • Efficiency and economy gains through recovery and recycling.

Legal Information

Pd EnCat® technology.
EnCat is a registered trademark of Reaxa Ltd.

signalword

Danger

Hazard Classifications

Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Sol. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 2 Inhalation

target_organs

Nervous system

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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