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660361

Sigma-Aldrich

CX21

Umicore, 98%

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Synonym(s):
Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II), (NHC)Pd(allyl)Cl, Allylchloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]palladium(II)
Empirical Formula (Hill Notation):
C30H41N2ClPd
CAS Number:
Molecular Weight:
571.53
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

98%

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

mp

>300 °C

SMILES string

[CH2][CH][CH2].CC(C)c1cccc(C(C)C)c1N2C=CN(C2[Pd]Cl)c3c(cccc3C(C)C)C(C)C

InChI

1S/C27H37N2.C3H5.ClH.Pd/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;1-3-2;;/h9-21H,1-8H3;3H,1-2H2;1H;/q;;;+1/p-1

InChI key

YVIDBHQABBIAAW-UHFFFAOYSA-M

General description

Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II) is an air-stable, well-defined palladium N-heterocyclic carbene complex, which can efficiently catalyze α-arylation of ketones.

Application

Catalyst for the arylation of ketones, Suzuki coupling reaction, Buchwald-Hartwig amination reaction, dehalogenation of aryl chlorides, and oxidation of secondary alcohols.

Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Well-defined, air-stable (NHC) Pd (Allyl) Cl (NHC= N-heterocyclic carbene) catalysts for the arylation of ketones.
Viciu MS, et al.
Organic Letters, 4(23), 4053-4056 (2002)

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