661724
Vinyltrimethylsilane
≥99.5%
Synonym(s):
Trimethyl(vinyl)silane, (Trimethylsilyl)ethylene, Ethenyltrimethylsilane
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About This Item
Linear Formula:
(CH3)3SiCHCH2
CAS Number:
Molecular Weight:
100.23
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
212-042-9
Beilstein/REAXYS Number:
956572
MDL number:
vapor pressure
4.44 psi ( 20 °C)
assay
≥99.5%
refractive index
n20/D 1.391 (lit.)
bp
55 °C (lit.)
density
0.684 g/mL at 25 °C (lit.)
SMILES string
C[Si](C)(C)C=C
InChI
1S/C5H12Si/c1-5-6(2,3)4/h5H,1H2,2-4H3
InChI key
GCSJLQSCSDMKTP-UHFFFAOYSA-N
Application
Preparation of silyl-ethers by Rh(I) catalysis.
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signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-11.2 °F
flash_point_c
-24 °C
ppe
Eyeshields, Faceshields, Gloves
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Jung-Woo Park et al.
Organic letters, 9(20), 4073-4076 (2007-09-11)
Highly efficient O-silylation of alcohol with vinylsilane was developed using a catalyst system consisting of [(COE)(2)RhCl](2) and HCl. In this reaction, a key intermediate is chlorosilane, generated from vinylsilane and HCl, which can be regenerated in the catalytic cycle. Various
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 661724-25G | 04061837838880 |