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Merck
CN

663069

(5R)-(+)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone monohydrochloride

97%

Synonym(s):

(5R)-2,2,3-Trimethyl-5-phenylmethyl-4-imidazolidinone monohydrochloride

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About This Item

Empirical Formula (Hill Notation):
C13H19ClN2O
CAS Number:
Molecular Weight:
254.76
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
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Product Name

(5R)-(+)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone monohydrochloride, 97%

InChI

1S/C13H18N2O.ClH/c1-13(2)14-11(12(16)15(13)3)9-10-7-5-4-6-8-10;/h4-8,11,14H,9H2,1-3H3;1H/t11-;/m1./s1

SMILES string

Cl.CN1C(=O)[C@@H](Cc2ccccc2)NC1(C)C

InChI key

YIYFEXGDFJLJGM-RFVHGSKJSA-N

assay

97%

form

solid

optical activity

[α]20/D +67°, c = 1 in H2O

mp

157-161 °C

functional group

phenyl

Quality Level

Application

Used in first highly enantioselective organocatalytic Diels-Alder reaction and 1,3-dipolar addition.

Legal Information

U.S. Pat. 6,369,243 and related patents apply. For research purposes only.

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Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Find documentation for the products that you have recently purchased in the Document Library.

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Ahrendt, K. A. et al
Journal of the American Chemical Society, 122, 4243-4243 (2000)
Jen, W. S. et al
Journal of the American Chemical Society, 122, 9874-9874 (2000)

Articles

Discover Professor David MacMillan's groundbreaking metal-free asymmetric catalysis using imidazolidinone-based organocatalysts for versatile transformations.

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